钢纤维混凝土钢筋锈蚀影响因子研究

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钢纤维混凝土钢筋锈蚀影响因子研究
摘要
钢筋混凝土结构耐久性问题愈来愈突出,解决混凝土结构耐久性问题意义重大
在混凝土耐久性损伤的众多原因中,由钢筋锈蚀引起的结构过早失效破坏表现的最
为突出。在一般大气环境中,混凝土结构的耐久性破坏主要源于混凝土的钢筋锈蚀
程度,因此本文重点研究混凝土的钢筋锈蚀问题。钢纤维混凝土 Steel Fiber
Reinforced Concrete,简称SFRC)指在混凝土中掺加钢纤维的新型复合材料,其极
大的提升了混凝土的物理性能,在多个指标上显著改良了传统的混凝土材料。
本文通过对SFRC进行钢筋锈蚀试验,同时联系了目前该领域的最新研究成果
探究了钢纤维对混凝土的增强机理,分析了钢纤维含量、钢筋直径、混凝土保护层
厚度、混凝土水灰比、外部环境因素等对SFRC的影响,提出了加速锈蚀条件下钢
筋锈蚀与各影响因子之间的函数关系,并以此分析各影响因子对钢筋锈蚀程度的影
响机理。本文开展的具体工作如下:
1)第一章介绍了钢筋锈蚀的研究背景和目前国内外SFRC钢筋锈蚀的研究现
状,进一步阐释了本文的研究内容和选题的重要意义。从微观角度研究了钢筋锈蚀
的电化学反应本质即锈蚀机理,同时归纳出钢筋锈蚀的常用检测方法。
2)第二~四章详细阐述半浸泡法钢筋加速锈蚀试验,包括试验方案、试验
材料和仪器,试验控制条件等,明确试验过程的详细步骤。同时基于大量试验,分
别对比了不同钢纤维掺量、钢筋直径、保护层厚度和水灰比的混凝土钢筋锈蚀电位
相对电位比和锈蚀电阻,并建立不同条件下钢筋锈蚀电位和电阻变化函数,直观的
反应了钢筋锈蚀程度和速率与不同影响因子之间的关系。试验表明:钢纤维掺量同
保护层厚度两个影响因子共同作用,影响钢筋的最终锈蚀程度;掺量为9%
SFRC的钢筋锈蚀电位要比掺量为1%的低50%,锈蚀级别小一级。在工程实践中,
可提高钢纤维掺量以减少混凝土中钢筋的锈蚀。钢筋直径越大,锈蚀电位越低,且
在大直径钢筋范围内,不同直径钢筋在锈蚀末期锈蚀电位差异不大(±15%),钢
筋直径同锈蚀速率存在正相关关系。在初始阶段的腐蚀,保护层厚度对钢筋腐蚀的
影响不大。在钢筋锈蚀的中期阶段,不同保护层厚度的试块钢筋锈蚀电位均大幅降
低,幅度大于50%,在锈蚀减阶段,钢筋电位电阻变化不分明显。保护层厚
度可效提升锈蚀起始时间。水灰比越小,水含量越高,混凝土的实性越
内部微细孔隙越小,能腐蚀介质、水分等的
,钢筋的腐蚀能越高。
3)第述了BP神经网络法和结构,阐述了神经网络处信息的决
因素。结合在加速锈蚀试验中所获取的大量试验数据样本,建立了加速锈蚀条件
下钢筋锈蚀电位锈蚀型,并对该型进行了相关验模拟结果显,该
算模测效果良
本文通过钢筋加速锈蚀试验,分析了各影响因子对混凝土钢筋锈蚀性能的作
用。同时,建立了钢筋锈蚀电位和电阻的型,为SFRC结构耐久性设计和分
析提试验和理论依据,以SFRC生产技术在工程实践中的推广和应
用。
键词SFRC 钢筋锈蚀 锈蚀机理 保护层 水灰比 电位
ABSTRACT
D u r a b i l i t y o f r e i n f o r c e d c o n c r e t e s t r u c t u r e s h a s b e c o m e m o r e p r o m i n e n t , s o
problems of solving du ra b i l i ty of conc r e t e struct ur es h ave been ve ry signific an t. The
s t r u c t u r a l s t e e l c o r r o s i o n h a s c a u s e d p r e m a t u r e f a i l u r e o f c o n c r e t e
s t r u c t u r e s , w h i c h i s t h e m o s t p r o m i n e n t d i s a s t e r i n a l l d u r a b i l i t y d a m a g e a n d
d e s t r u c t i o n . In th e g e n e r a l a t m o s p h e r e , t h e d a m a g e o f c o n c r e t e s t r u c t u r e s d u r a b i l i t y
mainly comes from concrete reinforcement corrosion, so the focus of this article is to
study the problem of reinforced concrete corrosion. As a kind of the new composite
m a t e r i a l w i t h st e e l f i b e r , st e e l f i b e r r e i n f o r c e d c o n c r e t e g r e a t l y
improves the physical performance of concrete, which means the new innovation in the
traditional areas of concrete materials.
B a s e d o n t h e t e s t s o f s t e e l f i b e r c o n c r e t e r e i n f o r c e m e n t c o r r o s i o n ,
and combined with the newest research results, this article explores the mechanism of
SFRC, and analyzes the impact of steel fiber content, concrete water-cement ratio, the
c o n c r e t e c o v e r t h i c k n e s s , r e b a r d i a m e t e r a n d e x t e r n a l e n v i r o n m e n t a l f a c t o r s o n
S F R C. T h e p a p e r p r e s e n ts t h e f u n c t i o ns b e t w e e n s t e e l c o r r o s i o n r a t e a n d v a r i o u s
influencing factors in the accelerated corrosion conditions, and analyzes the mechanism
how the influencing factors affect the degree of steel corrosion . In this paper, the
specific work will be carried out as follows
(1) T h e f i r s t c h a p t e r i n t r o d u c e s t h e r e s e a r c h b a c k g r o u n d o f s t e e l c o r r o s i o n
and current status of domestic and foreign steel fiber reinforced concrete corrosion
study, and explains the importance of content and topics. It studies the electrochemical
r e a c t i o n f r o m t h e m i c r o s c o p i c p o i n t o f v i e w w h i c h i s t h e n a t u r e o f t h e c o r r o s i o n
m e c h a n i s m o f s t e e l c o r r o s i o n a n d i t g e n e r a l i z e s t h e c o m m o n d e t e c t i o n w a y s o f s t e e l
corrosion.
( 2) T h e s e c o n d , t h i r d a n d f o u r t h c h a p t e rs e l a b o r a t e t h e t e s t o f s e m i - i m m e r s i o n
a c c e l e r a t e d c o r r o s i o n o f s t e e l , i n c l u d i n g t e s t p l a n , t e s t m a t e r i a l s a n d e q u i p m e n t ,
e x p e r i m e n t a l c o n t r o l c o n d i t i o n s , a n d d e t a i l e d s t e p s i n t h e t e s t p r o c e s s. T h e t h r e e
chapters use a large number of tests, respectively comparing the concrete reinforcement
c o r r o s i o n p o t e n t i a l, t h e r e l a t i v e p o t e n t i a l a n d c o r r o s i o n r e s i s t a n c e b e t w e e n d i f f e r e n t
s t e e l f i b e r c o n t e n ts, d i f f e r e n t b a r d i a m e t e rs, d i f f e r e n t p r o t e c t i v e l a y e r
thicknesses and different water-cement ratios, showing the functions between the extent
and rate of steel corrosion and different influencing factors. Tests show that The two
f a c t o r s i n c l u d i n g s t e e l f i b e r c o n t e n t a n d t h e p r o t e c t i v e l a y e r t h i c k n e s s
influence together, affecting the final corrosion potential of the test piece; 9% steel fiber
e x t e n t m e a n s 5 0 % s m a l l e r e x t e n t o f s t e e l c o r r o s i o n t h a n 1 % s t e e l f i b e r c o n t e n t ,
which means in engineering practice, people can improve the steel fiber content in order
to redu ce corrosion. The bigger the ba r di amete r is, the lowe r th e corrosi on p otential
is, and in the large-diameter steel range above 16mm, the difference of different
d i a m e t e r s t e e l c o r r o s i o n p o t e n t i a l i s n o t ob v i o u s ± 5 0 %,a n d t h e r e i s a p o s i t i v e
correlation between corrosion of steel with steel diameters; in the initial stage of steel
corrosion, the changes in the protective layer thickness affect little reinforced corrosion
rates. In the mid-phase of steel corrosion, steel corrosion potentials which comes from
t h e d i f f e r e n t t e s t p i e c e s o f s t e e l f i b e r c o n t e n t s i g n i f i c a n t l y
increases, some above 50%. In the decay phase of steel corrosion, steel potential and
resistance increased a little The protective layer thickness can effectively increase the
c o r r o s i o n i n i t i a t i o n t i m e ; t h e l o w e r t h e w a t e r - c e m e n t r a t i o i s, t h e h i g h e r t h e c e m e n t
content is, the better the density of concrete is, the smaller the tiny pores and capillary
channel is, the more external corrosion medium, such as oxygen and water infiltration,
c a n b e e f f e c t i v e l y p r e v e n te d a n d t h e h i g h e r t h e c o r r o s i o n r e s i s t a n c e o f s t e e l
is.
( 3 )T h e f i f t h c h a p t e r o u t l i n e s t h e s t r u c t u r e a n d a l g o r i t h m o f B P n e u r a l n e t w o r k ,
expounding the factors which decide neural network processing the information. With
the large number of test data samples in the accelerated corrosion test, it establishes the
p r e d i c t i o n m o d e l o f c o r r o s i o n p o t e n t i a l i n t h e c o n d i t i o n o f a c c e l e r a t e d c o r r o s i o n ,
t e s t i n g t h e c o r r o s i o n m o d e l . R e s e a r c h s h o w s t h a t , t h e m o d e l h a s a g o o d p r e d i c t i o n
effect.
By steel accelera ted corrosion tests, this paper a n alyzes the effect whic h va r ious
f a c t o r s h a v e o n t h e c o r r o s i o n p e r f o r m a n c e o f r e i n f o r c e d c o n c r e t e. I t e s t a b l i s he s t h e
p r e d i c t i o n m o d e l o f s t e e l c o r r o s i o n p o t e n t i a l a n d r e s i s t a n c e , w h i c h p r o v i d es
e x p e r i m e n t a l a n d t h e o r e t i c a l b a s i s f o r t h e s t r u c t u r e d u r a b i l i t y d e s i g n
and analysis of steel fiber reinforced concrete in order to promote the development of
steel fiber concrete production technology in the areas of engineering and applications.
Key Word steel fiber reinforced concrete, steel corrosion, corrosion
mechanism, protective layer, water-cement ratio, potential
中文
ABSTRACT
第一章 ............................................................................................................. 1
1.1研究背景选题意义...........................................................................................1
1.1.1混凝土结构耐久性........................................................................................1
1.1.2钢筋锈蚀危害及机理....................................................................................1
1.1.3研究钢筋锈蚀的意义....................................................................................4
1.2 SFRC钢筋锈蚀研究现状....................................................................................5
1.2.1应用....................................................................................................5
1.2.2国内外研究现状............................................................................................6
1.2.3常用检测方法................................................................................................7
1.3本文主要研究内容及技术路线...........................................................................8
第二章 钢纤维掺量对混凝土钢筋锈蚀影响研究.....................................................10
2.1.....................................................................................................................10
2.2试验设计.............................................................................................................10
2.2.1试验方案......................................................................................................10
2.2.2试验材料仪器..........................................................................................13
2.2.3试验步骤......................................................................................................15
2.2.4试验过程控制..............................................................................................16
2.3加速锈蚀过程中钢筋锈蚀电位变化..................................................................18
2.3.1原始数......................................................................................................18
2.3.2锈蚀电位变化分析......................................................................................19
2.3.3钢筋锈蚀电位与钢纤维掺量的关系..........................................................22
2.4加速锈蚀过程中钢筋锈蚀电阻变化.................................................................23
2.4.1原始数......................................................................................................23
2.4.2锈蚀电阻变化分析......................................................................................24
2.4.3钢筋锈蚀电阻与钢纤维掺量的关系..........................................................26
2.5本章小结.............................................................................................................27
钢筋直径对SFRC钢筋锈蚀影响研究...........................................................28
3.1.....................................................................................................................28
3.2试验设计........................................................................................................... 28
3.2.1试验方案......................................................................................................28
3.2.2试验控制......................................................................................................28
3.3加速锈蚀过程中锈蚀电位变化.........................................................................29
2.3.1原始数......................................................................................................29
2.3.2锈蚀电位变化分析......................................................................................29
2.3.3钢筋锈蚀电位与钢筋直径的关系..............................................................29
3.4本章小结.............................................................................................................29
第四章 混凝土设计参数对SFRC钢筋锈蚀影响研究...............................................33
4.1.....................................................................................................................33
4.2试验控制.............................................................................................................33
4.2.1保护层厚度设计及控制......................................................................33
4.2.2水灰比设计及控制..............................................................................34
4.3保护层厚度对钢筋锈蚀影响分析.....................................................................34
4.3.1不同保护层厚度钢筋锈蚀外观分析..........................................................34
4.3.2原始数......................................................................................................36
4.3.3钢筋锈蚀电位、电阻变化分析..................................................................37
4.3.4钢筋锈蚀电位、电阻同混凝土保护层厚度的关系..................................42
4.3.5..............................................................................................................44
4.4水灰比对钢筋锈蚀影响分析.............................................................................44
4.4.1原始数......................................................................................................44
4.4.2钢筋锈蚀电位、电阻变化分析..................................................................45
4.4.3钢筋锈蚀电位、电阻同混凝土水灰比的关系..........................................47
4.4.4..............................................................................................................48
4.5本章小结.............................................................................................................49
基于BP神经网络模型分析各影响因子对SFRC钢筋锈蚀的影响..............50
5.1.....................................................................................................................50
5.2 BP神经网络概...............................................................................................50
5.2.1 BP神经网络法和结构........................................................................50
5.2.2 BP神经网络处信息因素................................................................51
5.3计算模型的建立.................................................................................................53
5.3.1本来源......................................................................................................53
5.3.2函数......................................................................................................53
5.3.3点数..................................................................................................54
5.3.4训练函数......................................................................................................55
5.4计算结果分析.............................................................................................56
5.5本章小结.............................................................................................................57
与展.....................................................................................................59
6.1.................................................................................................................59
6.2.................................................................................................................60
参考......................................................................................................................61
第一章 绪论
第一章 绪论
1.1 研究背景选题意义
1.1.1 混凝土结构耐久性
混凝土结构包含素混凝土结构、凝土结构和钢筋混凝土结构三种
型。尽管混凝土的出现过一时间由于混凝土结构具体性
,材料来广泛,因域中
在建工程中,钢筋混凝了混凝土高的了钢
抗拉强度高的优势同时混凝与钢,钢又受凝土
保护,从提升了混凝土构物的工作性能。
随着社会经济展和们生产生,各、基设施
兴未钢筋混凝土结构的广泛使使土结构耐久性成为的问
混凝土结构耐久性设计规 GB/T 50476-2008)中对结构耐久性的
设计的环作用和维使条件下,混凝土结构件设计使年限
用性和安全性的能
1.1.2 钢筋锈蚀危害及机理
1.1.2.1 钢筋锈蚀对混凝土结构的危害
钢筋混凝结构广使得筋锈蚀问突出钢筋锈蚀
了混凝土结构的正常工作性要体现在:第一,钢筋净截面积减少使
的物学性能下降 [1]。第二,锈蚀钢筋与混凝土之间的结度
降。,锈膨胀保护层混凝土生逐变大压力外部护层
到更力更于开裂甚至剥保护混凝土损伤,钢筋与混凝土
结强,不响结构的正常使甚至
民经济造成重大损失[2]
结构损伤的事故很多源于钢混结构耐久性不,其中由于钢筋锈蚀导致
工程结构失效的情形广泛存在,来了大的经济损失。
4000 亿以上,其中大部分由钢筋锈蚀引起的,加上桥梁、机等工程
的维修费则更高。物如华盛顿林肯纪念馆杰弗逊纪
出现[3]线
受盐[4]线使
年受海洋盐雾环境影响,桥梁每年都需要进行维
[5]
阿拉伯海湾地区,其特殊环境,一般气 2050湿度大
水和混凝量高,钢混凝土结构锈使寿命只
1015 [6]
国,锈蚀导致耐久损失。研究表明,致我
国钢混结构耐久性失效的主要原因之一即为钢筋锈蚀。2000 年全年由腐
1800 亿损失,钢筋锈蚀其中 40%西使
20 即出现钢筋重锈蚀,最后致使拆除 [7]1984 年调查浙江沿海
1
摘要:

钢纤维混凝土钢筋锈蚀影响因子研究摘要钢筋混凝土结构耐久性问题愈来愈突出,解决混凝土结构耐久性问题意义重大在混凝土耐久性损伤的众多原因中,由钢筋锈蚀引起的结构过早失效破坏表现的最为突出。在一般大气环境中,混凝土结构的耐久性破坏主要源于混凝土的钢筋锈蚀程度,因此本文重点研究混凝土的钢筋锈蚀问题。钢纤维混凝土(SteelFiberReinforcedConcrete,简称SFRC)指在混凝土中掺加钢纤维的新型复合材料,其极大的提升了混凝土的物理性能,在多个指标上显著改良了传统的混凝土材料。本文通过对SFRC进行钢筋锈蚀试验,同时联系了目前该领域的最新研究成果探究了钢纤维对混凝土的增强机理,分析了钢纤...

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